Organometallic chemistry is the
study of organometallic compounds, chemical compounds containing at least one
chemical bond between a carbon atom of an organic molecule and a metal,
including alkaline, alkaline earth, and transition metals, and sometimes
broadened to include metalloids like boron, silicon, and tin, as well. Aside
from bonds to organyl fragments or molecules, bonds to 'inorganic' carbon, like
carbon monoxide (metal carbonyls), cyanide, or carbide, are generally
considered to be organometallic as well. Some related compounds such as
transition metal hydrides and metal phosphine complexes are often included in discussions
of organometallic compounds, though strictly speaking, they are not necessarily
organometallic. The related but distinct term "metalorganic compound"
refers to metal-containing compounds lacking direct metal-carbon bonds but
which contain organic ligands. Metal β-diketonates, alkoxides, dialkylamides,
and metal phosphine complexes are representative members of this class. The
field of organometallic chemistry combines aspects of traditional inorganic and
organic chemistry.
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